At 25°C, the standard enthalpy for the conversion of graphite to diamond is +1.895 kJ and the change in the standard entropy for this reaction is -3.363 J/K. Based on these data
A. graphite cannot be converted to diamond at 1 atm pressure.
B. diamond is more stable than graphite at all T's at one atmosphere.
C. diamond is more stable than graphite below 290°C and graphite is more stable than diamond above this T.
D. graphite is more stable than diamond below 290°C and diamond is more stable than graphite above 290°C.
At 25°C, the standard enthalpy for the conversion of graphite to diamond is +1.895 kJ and the change in the..
to happen spontaneously we want a dG = -
dG = dH - T(dS)
dG = +1.895 kJ - T( -3.363 J/K)
@ no temperature can dG = -
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A. TRUE : graphite cannot be converted to diamond at 1 atm pressure.
B. FALSE: diamond is more stable than graphite at all T's at one atmosphere.
C. FALSE: diamond is more stable than graphite below 290°C and graphite is more stable than diamond above this T.
D. FALSE: graphite is more stable than diamond below 290°C and diamond is more stable than graphite above 290°C.
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